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chainstretcher -> RE: Octane, Compression Ratio, and Detonation. (9/18/2006 5:15:42 PM)
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Sorry dude but I don't think that's the case. There are at least three major ways to measure octane for the pump and depending on where you live in the world determines what formula they post on the pumps. In the U.S. we use the R+M/2. You guys may use the RON only -- you'd have to check the sticker on the pump to see. There is no way I know of to compare them unless they are using the same formula for the rating. Here's an article that I've posted here before that explains it in non-engineering terms. I thinks it's an excellent read if you like that sort of stuff. Of course my 14 year old man-child tells me I'm a geek[8|] quote:
The octane number assigned to a motor fuel has very little to do with the actual chemical "octanes" in the fuel and everything to do with how well the fuel resists detonation (which is directly related to the amount of energy (heat) required to get the fuel burning in the first place). Therefore, it is possible to assign octane VALUES to fuel which contain no octanes whatsoever. WHY DO WE CARE ABOUT OCTANE? WHAT IS PREIGNITION? WHAT IS DETONATION? The octane value of a fuel is an empirical measure of its ability to resist detonation and, to a limited extent, preignition. Technically, octane ratings measure a fuel's ability to resist the spontaneous ignition of unburnt end-gases under controlled test conditions. What is preignition? Preignition occurs when the fuel/air mixture in a cylinder ignites before the spark plug fires. It can be caused by burning contaminates (such as carbon, or a spark plug of the wrong heat range) in the cylinder or by extreme overheating. What is detonation? Detonation occurs when the flame-front in a cylinder does not proceed smoothly from the point of ignition (the spark plug) to the opposite side of the cylinder. It refers to the spontaneous ignition of the entire charge in the cylinder. This ignition is often caused by the extreme pressure rise in the cylinder that occurs when the charge is first ignited (by the spark plug). WHAT ABOUT FUELS? There are six things to consider when comparing hydrocarbon fuels: 1. Volatility. In short, what's the fuel's propensity to vaporize. This effects the ability to easily mix the fuel with air and the fuel's tendency to vapor-lock. It also determines the pollution characteristics of the fuel where evaporative pollution is a concern. 2. Pre-ignition & knock resistance. Referred to as "Octane value." How much energy does it take to get the fuel burning - how much does it resist auto-ignition from compressive heat? Also, what is the rate of burn of the fuel (which affects the rate of pressure rise)? 3. Energy content. How much energy can be extracted from the fuel as a percentage of its volume or mass. 4. Heat of evaporation. 5. Chemical stability, neutrality, and cleanliness. What additives does the fuel contain to retard gum formation? Prevent icing? Prevent corrosion? Reduce deposits? 6. Safety The first three factors are often confused and interrelated when, in fact, they measure three completely separate things. There is no natural collelation between them. General rules: Heavy fuels (diesel, jet): Low volatility, low knock resistance, high energy per volume Light fuels (gasoline): High volatility, high knock resistance, low energy per volume Note that gasoline, partially, makes up for its (relatively) low energy-per gallon by the fact that a gallon of gasoline weighs less (by about 15%) than a gallon of jet fuel. Octane rating is in no way correlated with engine power or efficiency. There is more potential energy in a gallon of diesel fuel than a gallon of gasoline, yet the diesel fuel has a much lower octane value (more on that below). HOW DO YOU DETERMINE OCTANE? Ok, then, how is octane rating determined? First, you go out and get a suitable supply of the fuel which you wish to test. Then,
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